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class="jwpf-column" ><div id="nxdf3dp" class="jwpf-column-addons"><div class="5hd5rvx" id="jwpf-addon-wrapper-1617944403994" class="jwpf-addon-wrapper"><div class="hp5r75j" id="jwpf-addon-1617944403994" class="clearfix " > <style type="text/css"> @font-face { font-family: "Founder_small_label_Song_Simplified"; src: url("/components/com_jwpagefactory/addons/JZT_ADDON_LSGA_4D2L2F02N8/assets/css/5cbc27d3823fa.woff") format("woff"), url("/components/com_jwpagefactory/addons/JZT_ADDON_LSGA_4D2L2F02N8/assets/css/5cbc27d3823fa.ttf") format("truetype"), url("/components/com_jwpagefactory/addons/JZT_ADDON_LSGA_4D2L2F02N8/assets/css/5cbc27d3823fa.svg") format("svg"); } @font-face { font-family: "imitate_song"; src: url("/components/com_jwpagefactory/addons/JZT_ADDON_LSGA_4D2L2F02N8/assets/css/1653883165.woff") format("woff"), url("/components/com_jwpagefactory/addons/JZT_ADDON_LSGA_4D2L2F02N8/assets/css/1653883165.ttf") format("truetype"), 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#jwpf-addon-1617944403994 #JZT_ADDON_LSGA_4D2L2F02N8_TXT img { display: inline-block !important; max-width: 100% !important; height: auto !important; } }</style><div class="zz7ln1r" id="JZT_ADDON_LSGA_4D2L2F02N8_TXT"> <h2 style="text-align:center">雙堿法脫硫技術(shù)</h2> <hr /> <p style="text-align:right; display:block; padding-right:10px; color:#888888">編輯：2023-10-24 14:28:21</p> <div id="r15h77b" class="article-content" style="color:#555555;margin-top:15px"> <p style="text-indent: 2em; text-align: left; line-height: 2em;">雙堿法是采用鈉基脫硫劑進(jìn)行塔內脫硫，由于鈉基脫硫劑堿性強，吸收二氧化硫后反應產(chǎn)物溶解度大，不會(huì )造成過(guò)飽和結晶，造成結垢堵塞問(wèn)題。</p><p style="text-indent: 2em; text-align: left;"><img src="http://localhost/resource/kindeditor/attached/image/20180113/20180113100910_80425.jpg" alt="" style="border: 0px; vertical-align: bottom; float: left;" _src="http://localhost/resource/kindeditor/attached/image/20180113/20180113100910_80425.jpg"></p><p style="text-indent: 2em; text-align: left; line-height: 2em;">雙堿法脫硫技術(shù)工藝基本原理</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">雙堿法是采用鈉基脫硫劑進(jìn)行塔內脫硫，由于鈉基脫硫劑堿性強，吸收二氧化硫后反應產(chǎn)物溶解度大，不會(huì )造成過(guò)飽和結晶，造成結垢堵塞問(wèn)題。另一方面脫硫產(chǎn)物被排入再生池內用氫氧化鈣進(jìn)行還原再生，再生出的鈉基脫硫劑再被打回脫硫塔循環(huán)使用。雙堿法脫硫工藝降低了投資及運行費用，比較適用于中小型鍋爐進(jìn)行脫硫改造。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">雙堿法煙氣脫硫技術(shù)是利用氫氧化鈉溶液作為啟動(dòng)脫硫劑，配制好的氫氧化鈉溶液直接打入脫硫塔洗滌脫除煙氣中SO2來(lái)達到煙氣脫硫的目的，然后脫硫產(chǎn)物經(jīng)脫硫劑再生池還原成氫氧化鈉再打回脫硫塔內循環(huán)使用。脫硫工藝主要包括5個(gè)部分：(1)吸收劑制備與補充；(2)吸收劑漿液噴淋；(3)塔內霧滴與煙氣接觸混合；(4)再生池漿液還原鈉基堿；(5)石膏脫水處理。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">雙堿法煙氣脫硫工藝同石灰石/石灰等其他濕法脫硫反應機理類(lèi)似，主要反應為煙氣中的SO2先溶解于吸收液中，然后離解成H+和HSO3-；使用Na2CO3或NaOH液吸收煙氣中的SO2，生成HSO31-、SO32-與SO42-，反應方程式如下：</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">脫硫反應</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">Na2CO3 + SO2 → Na2SO3 + CO2↑ （1）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2NaOH + SO2 → Na2SO3 + H2O （2）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">Na2SO3+ SO2 + H2O → 2NaHSO3 （3）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">其中：</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">式（1）為啟動(dòng)階段Na2CO3溶液吸收SO2的反應；</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">式（2）為再生液pH值較高時(shí)（高于9時(shí)），溶液吸收SO2的主反應；</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">式（3）為溶液pH值較低（5~9）時(shí)的主反應。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">再生過(guò)程</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">Ca(OH)2+Na2SO3→2NaOH+CaSO3（4）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">Ca(OH)2+2NaHSO3→Na2SO3+CaSO3.1/2H2O+3/2H2O（5）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、氧化過(guò)程(副反應)</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">CaSO3+1/2O2→CaSO4（6）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">CaSO3.1/2H2O+1/2O2→CaSO4+1/2H2O（7）</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">雙堿法脫硫技術(shù)工藝特點(diǎn)</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">1、脫硫效率90%以上。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2、脫硫劑采用鈉堿和石灰，塔內清液吸收，有效避免塔內結垢。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、液氣比小?？擅摿虺龎m一體化。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">4、一次投資省，運行成本低，國產(chǎn)程度高。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">5、適應范圍廣。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">本公司就是從事廢氣廢水治理及節能技術(shù)改造的綜合服務(wù)商，如有需要請咨詢(xún)我們山西維杰爾環(huán)?？萍加邢薰?，環(huán)境保護謝謝你的參與。</p><p><br></p><p style="text-indent: 2em; text-align: left; line-height: 2em;">山西維杰爾環(huán)?？萍加邢薰?nbsp;</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">0351-7631946</p><p><br style="text-indent: 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