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#jwpf-addon-1617944403994 #JZT_ADDON_LSGA_4D2L2F02N8_TXT img { display: inline-block !important; max-width: 100% !important; height: auto !important; } }</style><div class="3j11fx9" id="JZT_ADDON_LSGA_4D2L2F02N8_TXT"> <h2 style="text-align:center">電鍍廢水處理</h2> <hr /> <p style="text-align:right; display:block; padding-right:10px; color:#888888">編輯：2023-10-24 14:26:45</p> <div id="nrldx7h" class="article-content" style="color:#555555;margin-top:15px"> <p style="text-indent: 2em; text-align: left; line-height: 2em;">電鍍生產(chǎn)排出的廢水或廢液的處理。電鍍工廠(chǎng)排出的廢水和廢液中含有大量金屬離子如：鉻、鎬、鎳，含氰，含酸，含堿，一般常含有有機添加劑。金屬離子有的以簡(jiǎn)單的陽(yáng)離子形式存在，有的則以酸根陰離于形式存在，有的以復雜的絡(luò )合離子存在。電鍍廢水處理常用中和沉淀法、中和混凝沉淀法、<span style="text-indent: 2em;">氧化法、還原法、鋇鹽法、鐵氧體法等化學(xué)方法?；瘜W(xué)法設備簡(jiǎn)單，投資少，應用較廣，但常留下污泥需要進(jìn)一步處理。</span></p><p style="text-indent: 2em; text-align: left;"><img src="http://localhost/resource/kindeditor/attached/image/20180202/20180202121737_30148.jpg" alt="" style="border: 0px; vertical-align: bottom; float: left;" _src="http://localhost/resource/kindeditor/attached/image/20180202/20180202121737_30148.jpg"></p><p style="text-indent: 2em; text-align: left; line-height: 2em;"><span style="text-indent: 2em;">電鍍廢水的來(lái)源</span><br></p><p style="text-indent: 2em; text-align: left; line-height: 2em;">電鍍生產(chǎn)中產(chǎn)生的廢水成分非常復雜，除含氰(CN-)和酸堿外，重金屬是電鍍業(yè)潛在危害性極大的污水類(lèi)別，這些物質(zhì)嚴重危害環(huán)境和人類(lèi)身體健康。電鍍廢水的主要來(lái)源有：</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">1、鍍件清洗水(是主要的廢水來(lái)源)。該廢水中除含重金屬離子外，還含有少量的有機物，其含量較低，但數量較大。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2、鍍液過(guò)濾沖洗水和廢鍍液的排放。這部分廢水數量不大，但含量高，污染大。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、工藝操作和設備、工藝流程中等造成的“跑、冒、滴、漏”排放的廢液。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">4、沖洗設備、地坪等產(chǎn)生的廢水。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">電鍍污水的治理在國內外普遍受到重視，已研制出多種治理技術(shù)，通過(guò)將有毒治理為*、有害轉化為無(wú)害、回收貴重金屬、水循環(huán)使用等措施*和減少污染物的排放量。隨著(zhù)電鍍工業(yè)的快速發(fā)展和環(huán)保要求的日益提高，目前電鍍污水治理已開(kāi)始進(jìn)入清潔生產(chǎn)工藝、總量控制和循環(huán)經(jīng)濟整合階段，資源回收利用和閉路循環(huán)是發(fā)展的主流方向。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">處理方法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">目前，我國處理電鍍廢水常用的方法有化學(xué)法、生物法、物化法和電化學(xué)法等。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">化學(xué)法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">化學(xué)法是依靠氧化還原反應或中和沉淀反應將有毒有害的物質(zhì)分解為*無(wú)害的物質(zhì)，或者直接將重金屬經(jīng)沉淀或氣浮從廢水中除去。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">1、沉淀法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">(1) 中和沉淀法。在含重金屬的廢水中加入堿進(jìn)行中和反應，使重金屬生成不溶于水的氫氧化物沉淀形式加以分離。中和沉淀法操作簡(jiǎn)單，是常用的處理廢水方法。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">(2) 硫化物沉淀法。加入硫化物使廢水中重金屬離子生成硫化物沉淀而除去的方法。與中和沉淀法相比，硫化物沉淀法的優(yōu)點(diǎn)是：重金屬硫化物溶解度比其氫氧化物的溶解度更低，反應pH值在7～9之間，處理后的廢水一般不用中和，處理*更好。但硫化物沉淀法的缺點(diǎn)是：硫化物沉淀顆粒小，易形成膠體，硫化物沉淀在水中殘留，遇酸生成氣體，可能造成二次污染。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">(3) 螯合沉淀法。通過(guò)高分子重金屬捕集沉淀劑(DTCR)在常溫下與廢水中Hg2+、Cd2+、Cu2+、Pb2+、Mn2+、Ni2+、Zn2+及Cr3+等重金屬離子迅速反應，生成不溶水的螯合鹽，再加入少量有機或(和)無(wú)機絮凝劑，形成絮狀沉淀，從而達到捕集去除重金屬的目的。DTCR系列藥劑處理電鍍廢水的特點(diǎn)是可同時(shí)去除多種重金屬離子，對重金屬離子以絡(luò )合鹽形式存在的情況，也能發(fā)揮良好的去除*，去除膠質(zhì)重金屬不受共存鹽類(lèi)的影響，具有較好的發(fā)展前景。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2、氧化法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">通過(guò)投加氧化劑，將電鍍廢水中有毒物質(zhì)氧化為*或低毒物，主要用于處理廢水中的CN-、Fe2+、Mn2+低價(jià)態(tài)離子及造成色度、昧、嗅的各種有機物以及致病微生物。如處理含氰廢水時(shí)，常用次氯酸鹽在堿性條件下氧化其中的氰離子，使之分解成低毒的氰酸鹽，然后再進(jìn)一步降解為*的二氧化碳和氮。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、化學(xué)還原法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">化學(xué)還原法在電鍍廢水治理中*典型的是對含鉻廢水的治理。其方法是在廢水中加入還原劑FeS04、NaHS03、Na2S03、S02或鐵粉等，使Cr(Ⅵ)還原成Cr(III)，然后再加入NaOH或石灰乳沉淀分離。該法優(yōu)點(diǎn)是設備簡(jiǎn)單、投資少、處理量大，但要防止沉渣污泥造成二次污染。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">4、中和法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">通過(guò)酸堿中和反應，調節電鍍廢水的酸堿度，使其呈中性或接近中性或適宜下步處理的酸堿度范圍，主要用來(lái)處理電鍍廠(chǎng)的酸洗廢水。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">5、氣浮法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">氣浮法作為處理電鍍廢水的技術(shù)是近幾年發(fā)展起來(lái)的一項新工藝。其基本原理是用高壓水泵將水加壓到幾個(gè)大氣壓注入溶罐中，使氣、水混合成溶氣水，溶氣水通過(guò)溶氣釋放器進(jìn)入水池中，由于突然減壓，溶解在水中的空氣形成大量微氣泡，與電鍍廢水初步處理產(chǎn)生的凝聚狀物黏附在一起，使其相對密度小于水而浮到水面上成為浮渣排除，從而使廢水得到凈化。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">生物法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">生物處理是一種處理電鍍廢水的新技術(shù)。一些微生物代謝產(chǎn)物能使廢水中的重金屬離子改變價(jià)態(tài)，同時(shí)微生物菌群本身還有較強的生物絮凝、靜電吸附作用，能夠吸附金屬離子，使重金屬經(jīng)固液分離后進(jìn)入菌泥餅，從而使得廢水達標排放或回用。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">1、生物吸附法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">凡具有從溶液中分離金屬能力的物體或生物體制備的衍生物稱(chēng)為生物吸附劑。生物吸附劑主要是菌體、藻類(lèi)及一些提取物。微生物對重金屬的吸附機理取決于許多物理、化學(xué)因素，如光、溫度、pH值、重金屬含量及化學(xué)形態(tài)、其他離子、螫合劑的存在和吸附劑的預處理等。生物吸附技術(shù)治理重金屬污染具有一定的優(yōu)勢，在低含量條件下，生物吸附劑可以選擇性地吸附其中的重金屬，受水溶液中鈣、鎂離子的干擾影響較小。該方法處理效率高，無(wú)二次污染，可有效地回收一些貴重金屬。但是生物成長(cháng)環(huán)境不容易控制，往往會(huì )因水質(zhì)的變化而大量中毒死亡。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2、生物絮凝法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">生物絮凝法是利用微生物或微生物產(chǎn)生的代謝物進(jìn)行絮凝沉淀的一種除污方法。微生物絮凝劑是由微生物自身產(chǎn)生的、具有*絮凝作用的天然高分子物質(zhì)，它的主要成分是糖蛋白、黏多糖、纖維素、蛋白質(zhì)和核酸等。它具有較高電荷或較強的親水性和疏水性，能與顆粒通過(guò)離子鍵、氫鍵和范德華力同時(shí)吸附多個(gè)膠體顆粒，在顆粒間產(chǎn)生架橋現象，形成一種網(wǎng)狀三維結構而沉淀下來(lái)。目前，對重金屬有絮凝作用的生物絮凝劑約有十幾個(gè)品種，生物絮凝劑中的氨基和羥基可與Cu 2+、Hg2+、Ag+、Au2+等重金屬離子形成穩定的螯合物而沉淀下來(lái)。該方法處理廢水具有安全方便*，不產(chǎn)生二次污染，絮凝范圍廣，絮凝活性高、生長(cháng)快，絮凝作用條件粗放，大多不受離子強度、pH值及溫度的影響，易于實(shí)現工業(yè)化等特點(diǎn)。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、生物化學(xué)法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">生物化學(xué)法是通過(guò)微生物與金屬離子之間發(fā)生直接的化學(xué)反應，將可溶性離子轉化為不溶性化合物而去除。其優(yōu)點(diǎn)是：選擇性強、吸附容量大、不使用化學(xué)藥劑。污泥中金屬含量高，二次污染明顯減少，而且污泥中重金屬易回收，回收率高。但其缺點(diǎn)是功能菌和廢水中金屬離子的反應效率并不高，且培養菌種的培養基消耗量較大，處理成本較高。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">物化法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">物化法是利用離子交換或膜分離或吸附劑等方法去除電鍍廢水所含的雜質(zhì)，其在工業(yè)上應用廣泛，通常與其他方法配合使用。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">1、離子交換法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">離子交換法是利用離子交換劑分離廢水中有害物質(zhì)的方法。*常用的交換劑是離子交換樹(shù)脂，樹(shù)脂飽和后可用酸堿再生后反復使用。離子交換是靠交換劑自身所帶的能自由移動(dòng)的離子與被處理的溶液中的離子通過(guò)離子交換來(lái)實(shí)現的。多數情況下，離子是先被吸附，再被交換，具有吸附、交換雙重作用。對于含鉻等重金屬離子的廢水，可用陰離子交換樹(shù)脂去除Cr(VI)，用陽(yáng)離子交換樹(shù)脂去除Cr(Ⅲ)、鐵、銅等離子。一般用于處理低有害物質(zhì)含量廢水，具有回收利用、化害為利、循環(huán)用水等優(yōu)點(diǎn)，但它的技術(shù)要求較高、一次性投資大。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2、膜分離法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">膜分離是指用半透膜作為障礙層，借助于膜的選擇滲透作用，在能量、含量或化學(xué)位差的作用下對混合物中的不同組分進(jìn)行分離。利用膜分離技術(shù)，可從電鍍廢水中回收重金屬和水資源，減輕或杜絕它對環(huán)境的污染，實(shí)現電鍍的清潔生產(chǎn)，對附加值較高的金、銀、鎳、銅等電鍍廢水用膜分離技術(shù)可實(shí)現閉路循環(huán)，并產(chǎn)生良好的經(jīng)濟效益。對于綜合電鍍廢水，經(jīng)過(guò)簡(jiǎn)單的物理化學(xué)法處理后，采用膜分離技術(shù)可回用大部分水，回收率可達60%～80%，減少污水總排放量，削減排放到水體中的污染物。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、蒸發(fā)濃縮法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">該方法是對電鍍廢水進(jìn)行蒸發(fā)，使重金屬廢水得以濃縮，并加以回收利用的一種處理方法，一般適用于處理含鉻、銅、銀、鎳等含重金屬的電鍍廢水。目前，一般將之作為其他方法的輔助處理手段。它具有能耗大、成本高、占地面積大、運轉費用高等缺點(diǎn)。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">4、活性炭吸附法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">活性炭吸附法是處理電鍍廢水的一種經(jīng)濟有效的方法，主要用于含鉻、含氰廢水。它的特點(diǎn)是處理調節溫和，操作安全，深度凈化的處理水可以回用。但該方法存在活性炭再生復雜和再生液不能直接回鍍槽利用的問(wèn)題，吸附容量小，不適于有害物含量高的廢水。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">電化學(xué)法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">1、電解法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">電解法是利用電解作用處理或回收重金屬，一般應用于貴金屬含量較高或單一的電鍍廢水。電解法處理Cr(VI)，是用鐵作電極，鐵陽(yáng)極不斷溶解產(chǎn)生的亞鐵離子能在酸性條件下將Cr(VI)還原成Cr(Ⅲ)，在陰極上Cr(Ⅵ)直接還原為Cr(Ⅲ)，由于在電解過(guò)程中要消耗氫離子，水中余留的氫氧根離子使溶液從酸性變?yōu)閴A性，并生成鉻和鐵的氫氧化物沉淀去除鉻。電解法能夠同時(shí)除去多種金屬離子，具有凈化*好、泥渣量少、占地面積小等優(yōu)點(diǎn)，但是消耗電能和鋼材較多，目前已較少采用。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">2、原電池法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">以顆粒炭、煤渣或其他導電惰性物質(zhì)為陰極，鐵屑為陽(yáng)極，廢水中導電電解質(zhì)起導電作用構成原電池，通過(guò)原電池反應來(lái)達到處理廢水的目的。近年來(lái)，鐵碳微電解技術(shù)在電鍍廢水的處理中受到越來(lái)越多的重視。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">3、電滲析法</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">電滲析技術(shù)是膜分離技術(shù)的一種。它是將陰、陽(yáng)離子交換膜交替地排列于正負電極之間，并用特制的隔板將其隔開(kāi)，在電場(chǎng)作用下，以電位差為推動(dòng)力，利用離子交換膜的選擇透過(guò)性，把電解質(zhì)從溶液中分離出來(lái)，從而實(shí)現電鍍廢水的濃縮、淡化、精制和提純。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">4、電凝聚氣浮法采用可溶性陽(yáng)極(Fe、AI等)材料，生成Fe2+、Fe3+、Al3+等大量陽(yáng)離子，通過(guò)絮凝生成Fe(OH)2、Fe(OH)3、AI(OH)3等沉淀物，以去除水中的污染物。同時(shí)，陰極上產(chǎn)生大量的H2微氣泡，陽(yáng)極上產(chǎn)生大量的O2微氣泡，以這些氣泡作為氣浮載體，與絮凝污物一起上浮。大量絮體在豐富的微氣泡攜帶下迅速上浮，達到凈化水質(zhì)的目的。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">我國電鍍廢水的常規處理技術(shù)已經(jīng)比較成熟，現代生物法處理電鍍廢水是非常有發(fā)展前途的一項廢水處理技術(shù)，且不產(chǎn)生二次污染，關(guān)鍵是要運用新技術(shù)對其進(jìn)行深度處理，進(jìn)一步提高出水水質(zhì)。膜處理技術(shù)因其分離效率高，且能回收重金屬，今后必將在電鍍廢水處理中占據重要的地位。同時(shí)通過(guò)推廣清潔生產(chǎn)工藝，從電鍍生產(chǎn)的各個(gè)環(huán)節上減少排污量，變“被動(dòng)治理”為“積極治理”，也是解決電鍍廢水污染的根本方法。</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">本公司就是從事廢氣廢水治理及節能技術(shù)改造的綜合服務(wù)商，如有需要請咨詢(xún)我們山西維杰爾環(huán)?？萍加邢薰?，環(huán)境保護謝謝你的參與。</p><p><br></p><p style="text-indent: 2em; text-align: left; line-height: 2em;">山西維杰爾環(huán)?？萍加邢薰?nbsp;</p><p style="text-indent: 2em; text-align: left; line-height: 2em;">0351-7631946</p><p><br style="text-indent: 2em; text-align: left;"></p> </div><style>#jwpf-addon-1617944403994 #JZT_ADDON_LSGA_4D2L2F02N8_TXT .article-content p { margin-top: 0px; margin-bottom: 16px; }#jwpf-addon-1617944403994 #JZT_ADDON_LSGA_4D2L2F02N8_TXT .btnBox, #jwpf-addon-1617944403994 #JZT_ADDON_LSGA_4D2L2F02N8_TXT .btnBoxt { display: flex; justify-content: 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